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/Peo, FreeWebSpace.net
Usually from webhosting control panel you will be able to click some icon to Add new domain to the account. Once added, you just upload files into proper directory of the hosting account.
Ofcourse hosting company have to allow multiple domains hosting on your hosting plan.
Just settle for a reliable host that charges a reasonably high rate and offers good service.
I know demontech.net is good choice for hosting multiple sites. It also offers excellent value for money with lost of great features for what I consider a very reasonable price.
First you should check your web hosting plan. If you want to host multiple sites on one account you need to make sure that there are multiple domains included into the plan.